Triallyl(aryl)silanes serve as a convenient agent for silicon-based cross-coupling reaction of aryl halides

dc.contributor.author	Nakao, Yoshiaki
dc.contributor.author	Oda, Takuro
dc.contributor.author	Sahoo, K. Akhila
dc.contributor.author	Hiyama, Tamejiro
dc.date.accessioned	2022-03-27T08:35:51Z
dc.date.available	2022-03-27T08:35:51Z
dc.date.issued	2003-12-07
dc.description.abstract	Triallyl(aryl)silanes, stable and easily accessible arylsilanes, were found to react with aryl bromides in the presence of a palladium catalyst (PdCl2-PCy3) and tetrabutylammonium fluoride (TBAF) in good yields. The scope of the reaction is broad, and a wide variety of functional groups are tolerant. Allyl groups on Si are readily cleaved upon treatment with TBAF to form fluorosilanes, silanepolyols, siloxanes and/or their mixed forms, which might be responsible for high efficiency of the reaction. © 2003 Elsevier B.V. All rights reserved.
dc.identifier.citation	Journal of Organometallic Chemistry. v.687(2)
dc.identifier.issn	0022328X
dc.identifier.uri	10.1016/j.jorganchem.2003.08.041
dc.identifier.uri	https://www.sciencedirect.com/science/article/abs/pii/S0022328X03009197
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/11115
dc.subject	Aryl bromide
dc.subject	Aryl iodide
dc.subject	Cross-coupling
dc.subject	Palladium
dc.subject	Triallyl(aryl)silane
dc.title	Triallyl(aryl)silanes serve as a convenient agent for silicon-based cross-coupling reaction of aryl halides
dc.type	Journal. Article
dspace.entity.type

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