Synthesis, structure and spectral studies on mixed ligand copper(II) complexes of diimines and acetylacetonate

dc.contributor.author	Onawumi, O. O.E.
dc.contributor.author	Faboya, O. O.P.
dc.contributor.author	Odunola, O. A.
dc.contributor.author	Prasad, T. K.
dc.contributor.author	Rajasekharan, M. V.
dc.date.accessioned	2022-03-27T09:16:02Z
dc.date.available	2022-03-27T09:16:02Z
dc.date.issued	2008-01-20
dc.description.abstract	Two new mixed ligand complexes of copper(II) with acetylacetonate (acac), 2,2′-bipyridine (bpy) and 1,10-phenanthroline (phen) belonging to the class of cytotoxic and antineoplastic compounds known as CASIOPEINAS® were synthesized and structurally characterized. Crystals of both complexes [Cu(acac)(bpy)(H2O)]NO3 · H2O (1), [Cu(acac)(phen)Br] (2) contain square pyramidal Cu(II) complex species. In frozen solution both compounds give well resolved EPR spectra with very similar parameters. © 2007 Elsevier Ltd. All rights reserved.
dc.identifier.citation	Polyhedron. v.27(1)
dc.identifier.issn	02775387
dc.identifier.uri	10.1016/j.poly.2007.08.041
dc.identifier.uri	https://www.sciencedirect.com/science/article/abs/pii/S0277538707005359
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/12672
dc.subject	Casiopeinas ®
dc.subject	Copper(II) complex
dc.subject	EPR spectroscopy
dc.subject	Mixed ligand chelate
dc.subject	UV-Vis spectroscopy
dc.title	Synthesis, structure and spectral studies on mixed ligand copper(II) complexes of diimines and acetylacetonate
dc.type	Journal. Article
dspace.entity.type

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