Isolation and structural characterization of 1,5-benzodiazepinium cation in an inorganic-organic hybrid compound [C < inf > 12 < /inf > H < inf > 17 < /inf > N < inf > 2 < /inf > ] < inf > 3 < /inf > [Bi < inf > 2 < /inf > Cl < inf > 9 < /inf > ]·2EtOH
Isolation and structural characterization of 1,5-benzodiazepinium cation in an inorganic-organic hybrid compound [C < inf > 12 < /inf > H < inf > 17 < /inf > N < inf > 2 < /inf > ] < inf > 3 < /inf > [Bi < inf > 2 < /inf > Cl < inf > 9 < /inf > ]·2EtOH
| dc.contributor.author | Rao, A. Srinivasa | |
| dc.contributor.author | Babu, Eadi Sunil | |
| dc.contributor.author | Swamy, K. C.Kumara | |
| dc.contributor.author | Das, Samar K. | |
| dc.date.accessioned | 2022-03-27T09:51:51Z | |
| dc.date.available | 2022-03-27T09:51:51Z | |
| dc.date.issued | 2010-04-19 | |
| dc.description.abstract | The compound [C12H17N2]3[Bi2Cl9]·2EtOH (1) has been synthesized from bismuth trichloride and o-phenylenediamine (opda) in ethanol at an aerial ambient condition. This preparation includes the conversion of opda to 2,3-dihydro-1H-1,5-benzodiazepinium cation through its reaction with acetone that is formed in situ from aerial ethanol oxidation. Compound 1 crystallizes in triclinic system (space group P-1). In the crystal structure of 1, the supramolecular hydrogen bonding interactions between [Bi2C9]3- and [C12H17N2]+ play an important role in the stabilization of cationic form of 2,3-dihydro-1H-1,5-benzodiazepine and in obtaining emission signals of the organic moiety, which is otherwise not emissive. Compound [C12H17N2]3[Bi2Cl9]·2(2-PrOH) (2), that has been isolated from 2-propanol (instead of ethanol), is isostructural with compound 1. © 2010 Elsevier Ltd. All rights reserved. | |
| dc.identifier.citation | Polyhedron. v.29(6) | |
| dc.identifier.issn | 02775387 | |
| dc.identifier.uri | 10.1016/j.poly.2010.02.014 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S0277538710000951 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/13383 | |
| dc.subject | Benzodiazepine | |
| dc.subject | Bismuth dimer | |
| dc.subject | Crystal structure | |
| dc.subject | Inorganic-organic hybrid compound | |
| dc.subject | Supramolecular interactions | |
| dc.title | Isolation and structural characterization of 1,5-benzodiazepinium cation in an inorganic-organic hybrid compound [C < inf > 12 < /inf > H < inf > 17 < /inf > N < inf > 2 < /inf > ] < inf > 3 < /inf > [Bi < inf > 2 < /inf > Cl < inf > 9 < /inf > ]·2EtOH | |
| dc.type | Journal. Article | |
| dspace.entity.type |
Files
License bundle
1 - 1 of 1