Reversible single crystal to single crystal transformation through Fe-O(H)Me/Fe-OH < inf > 2 < /inf > bond formation/bond breaking in a gas-solid reaction at an ambient condition
Reversible single crystal to single crystal transformation through Fe-O(H)Me/Fe-OH < inf > 2 < /inf > bond formation/bond breaking in a gas-solid reaction at an ambient condition
| dc.contributor.author | Supriya, Sabbani | |
| dc.contributor.author | Das, Samar K. | |
| dc.date.accessioned | 2022-03-27T08:44:02Z | |
| dc.date.available | 2022-03-27T08:44:02Z | |
| dc.date.issued | 2007-03-28 | |
| dc.description.abstract | A single crystal of an iron compound containing a Fe-OH2 bond, on exposure to methanol vapor at an ambient condition, transforms to another single crystal with the formation of a Fe-O(H)Me covalent bond at the cost of breaking the Fe-OH2 bond. The methanol complex, upon exposure to atmospheric water vapor at room temperature, goes back to an original water-coordinated complex. The full reversibility of this gas-solid system was established by X-ray crystallography and IR spectroscopy. Copyright © 2007 American Chemical Society. | |
| dc.identifier.citation | Journal of the American Chemical Society. v.129(12) | |
| dc.identifier.issn | 00027863 | |
| dc.identifier.uri | 10.1021/ja067572p | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/ja067572p | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/11638 | |
| dc.title | Reversible single crystal to single crystal transformation through Fe-O(H)Me/Fe-OH < inf > 2 < /inf > bond formation/bond breaking in a gas-solid reaction at an ambient condition | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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