Synthesis and structural characterization of a carboxylate bridged tetranuclear copper complex derived from reduced Schiff base asymmetric compartmental ligand containing an amino acid side arm
Synthesis and structural characterization of a carboxylate bridged tetranuclear copper complex derived from reduced Schiff base asymmetric compartmental ligand containing an amino acid side arm
| dc.contributor.author | Pradeep, Chullikkattil P. | |
| dc.contributor.author | Zacharias, Panthapally S. | |
| dc.contributor.author | Das, Samar K. | |
| dc.date.accessioned | 2022-03-27T08:44:10Z | |
| dc.date.available | 2022-03-27T08:44:10Z | |
| dc.date.issued | 2006-11-01 | |
| dc.description.abstract | The dinucleating asymmetric reduced Schiff base compartmental ligand H2L {2-[5-bromo-2-hydroxy-3-(4-methyl-piperazin-1-ylmethyl)-benzylamino]-propionic acid} (see Scheme 1 for H2L) gives the tetracopper(II) complex [Cu4L2(CH3COO)4] · 2CH3CN · 2H2O (1) on reaction with (CH3COO)2Cu · H2O. The single crystal X-ray structure of 1 reveals that this complex is a carboxylate bridged dimer of dinuclear copper(II) subunits, in which the copper(II) centers adopt different geometries, resulting in a {Cu4} complex. © 2006 Elsevier B.V. All rights reserved. | |
| dc.identifier.citation | Inorganic Chemistry Communications. v.9(11) | |
| dc.identifier.issn | 13877003 | |
| dc.identifier.uri | 10.1016/j.inoche.2006.06.019 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S1387700306002462 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/11644 | |
| dc.title | Synthesis and structural characterization of a carboxylate bridged tetranuclear copper complex derived from reduced Schiff base asymmetric compartmental ligand containing an amino acid side arm | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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