Silver(I)-catalyzed reaction between pyrazole and propargyl acetates: Stereoselective synthesis of the scorpionate ligands (E)-allyl-gem-dipyrazoles (ADPs)

dc.contributor.author	Bhanuchandra, M.
dc.contributor.author	Kuram, Malleswara Rao
dc.contributor.author	Sahoo, Akhila K.
dc.date.accessioned	2022-03-27T08:34:16Z
dc.date.available	2022-03-27T08:34:16Z
dc.date.issued	2013-12-06
dc.description.abstract	The reaction between readily accessible pyrazole and propargyl acetates in the presence of Ag(I) catalyst yielded a new class of (E)-allyl-gem-dipyrazole scorpionate ligands: 1-aryl-2-N-pyrazolyl allyl acetates and 1,3-dipyrazolyl-3-arylpropene. The reaction showed broad substrate scope, and various functional and protecting groups were tolerated under the reaction conditions. The palladium(II) scorpionate complex could thus be easily prepared and successfully employed in Suzuki-Miyaura cross-couplings in water. © 2013 American Chemical Society.
dc.identifier.citation	Journal of Organic Chemistry. v.78(23)
dc.identifier.issn	00223263
dc.identifier.uri	10.1021/jo401867e
dc.identifier.uri	https://pubs.acs.org/doi/10.1021/jo401867e
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/10904
dc.title	Silver(I)-catalyzed reaction between pyrazole and propargyl acetates: Stereoselective synthesis of the scorpionate ligands (E)-allyl-gem-dipyrazoles (ADPs)
dc.type	Journal. Article
dspace.entity.type

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