Experimental and computational (AMI, MNDO, PM3) studies on the hydrolysis rates of ethylene ketals in 1,3-cycIohexanediones

dc.contributor.author	Nangia, A.
dc.contributor.author	Chandrakala, P. S.
dc.date.accessioned	2022-03-27T09:35:12Z
dc.date.available	2022-03-27T09:35:12Z
dc.date.issued	1996-12-01
dc.description.abstract	The relative hydrolysis rates of cyclohexanone ethylene ketals having different substituents at the β-carbon, such as H2, (OCH2)2, (SCH2)2, =O, were determined at 20°C in aqueous H2SO2-siIica gel-CH2C2 medium. The observed kinetic trend of H2 (OCH2)2 (SCH?)2 =O is correlated with calculated AH values (AMI, MNDO and PM3)for the ionisation of substituted cyclohexanes to the corresponding cations.
dc.identifier.citation	Proceedings of the Indian Academy of Sciences: Chemical Sciences. v.108(1)
dc.identifier.issn	02534134
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/13083
dc.subject	β- Substituent effect
dc.subject	AMI calculations
dc.subject	Carbocation stability
dc.subject	Ketal hydrolysis
dc.title	Experimental and computational (AMI, MNDO, PM3) studies on the hydrolysis rates of ethylene ketals in 1,3-cycIohexanediones
dc.type	Journal. Article
dspace.entity.type

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