Supramolecular assembly based on a heteropolyanion: Synthesis and crystal structure of Na < inf > 3 < /inf > (H < inf > 2 < /inf > O) < inf > 6 < /inf > [Al(OH) < inf > 6 < /inf > Mo < inf > 6 < /inf > O < inf > 18 < /inf > ]·2H < inf > 2 < /inf > O

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dc.contributor.author Shivaiah, Vaddypally
dc.contributor.author Das, Samar K.
dc.date.accessioned 2022-03-27T08:44:27Z
dc.date.available 2022-03-27T08:44:27Z
dc.date.issued 2005-01-01
dc.description.abstract Synthesis and structural characterization of a polyoxometalate compound Na3(H2O)6 [Al(OH)6Mo 6O18]·2H2O (1) have been described. Compound 1 exhibits three-dimensional network structure in the solid state, which is assembled by Anderson-type heteropolyanions, [Al(OH)6Mo 6O18]n3n-, as building blocks sharing sodium cations. 1 possesses "sinuous" channels occupied by supramolecular water dimers as guests. Anderson anions, sodium-coordinated water and crystal water are additionally involved in an intricate hydrogen-bonding network in the crystal of 1. © Indian Academy of Sciences.
dc.identifier.citation Journal of Chemical Sciences. v.117(3)
dc.identifier.issn 02534134
dc.identifier.uri 10.1007/BF02709291
dc.identifier.uri http://link.springer.com/10.1007/BF02709291
dc.identifier.uri https://dspace.uohyd.ac.in/handle/1/11658
dc.subject Anderson-type heteropolyanions
dc.subject Guest supramolecular water dimers
dc.subject Hydrogen-bonding interactions
dc.subject Sodium cation as linkers
dc.subject Three-dimensional network structure
dc.title Supramolecular assembly based on a heteropolyanion: Synthesis and crystal structure of Na < inf > 3 < /inf > (H < inf > 2 < /inf > O) < inf > 6 < /inf > [Al(OH) < inf > 6 < /inf > Mo < inf > 6 < /inf > O < inf > 18 < /inf > ]·2H < inf > 2 < /inf > O
dc.type Journal. Article
dspace.entity.type
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