Applications of Baylis-Hillman coupling products: A remarkable reversal of stereochemistry from esters to nitriles: A simple synthesis of (2E)-2-methylalk-2-en-1-ols and (2Z)-2-methylalk-2-enenitriles
Applications of Baylis-Hillman coupling products: A remarkable reversal of stereochemistry from esters to nitriles: A simple synthesis of (2E)-2-methylalk-2-en-1-ols and (2Z)-2-methylalk-2-enenitriles
| dc.contributor.author | Basavaiah, Deevi | |
| dc.contributor.author | Sarma, Pakala K.S. | |
| dc.date.accessioned | 2022-03-27T09:04:58Z | |
| dc.date.available | 2022-03-27T09:04:58Z | |
| dc.date.issued | 1992-12-01 | |
| dc.description.abstract | Reaction of methyl 3-acetoxy-2-methylenealkanoates with the reducing agent, lithium aluminium hydride (LAH): ethanol (1 : 1), provides (2E)-2-methylalk-2- en-1-ols, whereas, reaction of 3-acetoxy-2-methylenealkanenitriles with the same reagent provides (2Z)-2-methylalk-2-enenitriles in high yields. | |
| dc.identifier.citation | Journal of the Chemical Society, Chemical Communications | |
| dc.identifier.issn | 00224936 | |
| dc.identifier.uri | 10.1039/C39920000955 | |
| dc.identifier.uri | http://xlink.rsc.org/?DOI=C39920000955 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12384 | |
| dc.title | Applications of Baylis-Hillman coupling products: A remarkable reversal of stereochemistry from esters to nitriles: A simple synthesis of (2E)-2-methylalk-2-en-1-ols and (2Z)-2-methylalk-2-enenitriles | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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