Total synthesis of (±)-β-microbiotene, (±)-microbiotol, (±)-cyclocuparanol and (±)-β-cuparenones
Total synthesis of (±)-β-microbiotene, (±)-microbiotol, (±)-cyclocuparanol and (±)-β-cuparenones
| dc.contributor.author | Srikrishna, A. | |
| dc.contributor.author | Ramachary, D. B. | |
| dc.date.accessioned | 2022-03-27T09:41:57Z | |
| dc.date.available | 2022-03-27T09:41:57Z | |
| dc.date.issued | 2007-05-01 | |
| dc.description.abstract | Total synthesis of (±)-β-microbiotene, (±)-microbiotol, (±)-cyclocuparanol and their epimers along with (±)-β- cuparenone has been described. A combination of orthoester Claisen rearrangement, an acid catalysed rearrangement of a diazoketone for the generation of bicyclo[4.2.1]nonanedione, a retro-Claisen condensation and an intramolecular diazoketone cyclopropanation reaction have been employed for the construction of three contiguous quaternary atoms present in cyclocuparanes. | |
| dc.identifier.citation | Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry. v.46(5) | |
| dc.identifier.issn | 03764699 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/13210 | |
| dc.subject | Cuparenes | |
| dc.subject | Cyclocuparanes | |
| dc.subject | Cyclopropanation | |
| dc.subject | Diazo ketones | |
| dc.subject | Rearrangement | |
| dc.subject | Sesquiterpene synthesis | |
| dc.title | Total synthesis of (±)-β-microbiotene, (±)-microbiotol, (±)-cyclocuparanol and (±)-β-cuparenones | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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