Synthesis of 1-arylnaphthalenes by gold-catalyzed one-pot sequential epoxide to carbonyl rearrangement and cyclization with arylalkynes
Synthesis of 1-arylnaphthalenes by gold-catalyzed one-pot sequential epoxide to carbonyl rearrangement and cyclization with arylalkynes
| dc.contributor.author | Gudla, Vanajakshi | |
| dc.contributor.author | Balamurugan, Rengarajan | |
| dc.date.accessioned | 2022-03-27T08:39:26Z | |
| dc.date.available | 2022-03-27T08:39:26Z | |
| dc.date.issued | 2013-02-01 | |
| dc.description.abstract | Intermolecular and intramolecular reactions of a one-pot gold-catalyzed epoxide rearrangement followed by an electrophilic addition to arylalkynes to synthesize 1-arylnaphthalenes have been reported. The intramolecular reaction has been applied to synthesize 1-arylnaphthalenes fused with saturated furan, pyran, pyrrole, and cyclopentane ring systems. A gold-catalyzed regioselective one-pot synthesis of 1-arylnaphthalenes from aryl epoxides has been presented. Both intermolecular and intramolecular cyclizations have been demonstrated. The intramolecular reactions provided 1-arylnaphthalenes fused with saturated furan/pyran/pyrrole/cyclopentane ring systems. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | |
| dc.identifier.citation | Chemistry - An Asian Journal. v.8(2) | |
| dc.identifier.issn | 18614728 | |
| dc.identifier.uri | 10.1002/asia.201200817 | |
| dc.identifier.uri | https://onlinelibrary.wiley.com/doi/10.1002/asia.201200817 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/11387 | |
| dc.subject | 1-arylnaphthalene | |
| dc.subject | alkynes | |
| dc.subject | electrophilic addition | |
| dc.subject | gold | |
| dc.subject | rearrangement | |
| dc.title | Synthesis of 1-arylnaphthalenes by gold-catalyzed one-pot sequential epoxide to carbonyl rearrangement and cyclization with arylalkynes | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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