Synthesis of Novel Hexaazaisowurtzitane Cages to Access CL-20
Synthesis of Novel Hexaazaisowurtzitane Cages to Access CL-20
| dc.contributor.author | Aravindu, Pampuram | |
| dc.contributor.author | Rani, Karike Durga | |
| dc.contributor.author | Shaik, Abdul Munaf | |
| dc.contributor.author | Kommu, Nagarjuna | |
| dc.contributor.author | Rao, Vepa Kameswara | |
| dc.date.accessioned | 2022-03-27T01:10:22Z | |
| dc.date.available | 2022-03-27T01:10:22Z | |
| dc.date.issued | 2022-01-01 | |
| dc.description.abstract | A novel hexacyclopropylhexaazaisowurtzitane (HCPIW) and hexacyclobutylhexaazaisowurtzitane (HCBIW) cage compounds were synthesized using a straightforward method by reacting glyoxal with the corresponding cycloalkylamines such as cyclopropylamine and cyclobutylamine in the presence of a catalytic amount of an acid. The obtained compounds were characterized in detail by spectroscopic and X-ray diffraction analyses. HCPIW and HCBIW with 99% and 98% purity were obtained without column chromatography. Nitration of HCPIW with H2SO4/HNO3 in dichloromethane solvent successfully afforded CL-20, high energy propellant and explosive in 25% yield. | |
| dc.identifier.citation | Asian Journal of Organic Chemistry. v.11(1) | |
| dc.identifier.issn | 21935807 | |
| dc.identifier.uri | 10.1002/ajoc.202100680 | |
| dc.identifier.uri | https://onlinelibrary.wiley.com/doi/10.1002/ajoc.202100680 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/4113 | |
| dc.title | Synthesis of Novel Hexaazaisowurtzitane Cages to Access CL-20 | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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