Decavanadates with [Et < inf > 3 < /inf > NH] + and [Me < inf > 2 < /inf > HN(CH < inf > 2 < /inf > ) < inf > 2 < /inf > NHMe < inf > 2 < /inf > ] 2+ : Variation in protonation state and self-assembly

dc.contributor.author	Sarkar, Anindita
dc.contributor.author	Pal, Samudranil
dc.date.accessioned	2022-03-27T08:46:46Z
dc.date.available	2022-03-27T08:46:46Z
dc.date.issued	2008-11-25
dc.description.abstract	Synthesis, thermal behaviour and crystal structures of [Et3NH]4[V10O26(OH)2] (1) and [Me2HN(CH2)2NHMe2]3[V10O28] · 4H2O (2) are reported. In the crystal lattice of 1, the anions form discrete dimers via O-H···O hydrogen bonds and the cations are connected to the respective anions through N-H···O hydrogen bonds. On the other hand, 2 forms a complex three-dimensional network due to involvement of the cations, the anions and the lattice water in O-H···O and N-H···O hydrogen bonds. © 2008 Elsevier Ltd. All rights reserved.
dc.identifier.citation	Polyhedron. v.27(17)
dc.identifier.issn	02775387
dc.identifier.uri	10.1016/j.poly.2008.08.001
dc.identifier.uri	https://www.sciencedirect.com/science/article/abs/pii/S0277538708004154
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/11763
dc.subject	Ammonium and diammonium
dc.subject	Crystal structures
dc.subject	Decavanadates
dc.subject	Dimeric aggregates
dc.subject	Three-dimensional network
dc.title	Decavanadates with [Et < inf > 3 < /inf > NH] < sup > + < /sup > and [Me < inf > 2 < /inf > HN(CH < inf > 2 < /inf > ) < inf > 2 < /inf > NHMe < inf > 2 < /inf > ] < sup > 2+ < /sup > : Variation in protonation state and self-assembly
dc.type	Journal. Article
dspace.entity.type

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Decavanadates with [Et < inf > 3 < /inf > NH] < sup > + < /sup > and [Me < inf > 2 < /inf > HN(CH < inf > 2 < /inf > ) < inf > 2 < /inf > NHMe < inf > 2 < /inf > ] < sup > 2+ < /sup > : Variation in protonation state and self-assembly