Vinyl azides derived from allenes: Thermolysis leading to multisubstituted 1,4-pyrazines and Mn(III)-catalyzed photochemical reaction leading to pyrroles
Vinyl azides derived from allenes: Thermolysis leading to multisubstituted 1,4-pyrazines and Mn(III)-catalyzed photochemical reaction leading to pyrroles
| dc.contributor.author | Sajna, K. V. | |
| dc.contributor.author | Swamy, K. C.Kumara | |
| dc.date.accessioned | 2022-03-27T09:50:49Z | |
| dc.date.available | 2022-03-27T09:50:49Z | |
| dc.date.issued | 2012-10-05 | |
| dc.description.abstract | Thermolysis of phosphorus-based vinyl azides under solvent- and catalyst-free conditions furnished a new route for 1,4-pyrazines. A simple one-pot, Mn(III)-catalyzed photochemical route has been developed for multisubstituted pyrroles starting from allenes and 1,3-dicarbonyls via in situ-generated vinyl azides. The utility of new phosphorus-based pyrroles is also demonstrated in the Horner reaction. The structures of key products are unequivocally confirmed by X-ray crystallography. © 2012 American Chemical Society. | |
| dc.identifier.citation | Journal of Organic Chemistry. v.77(19) | |
| dc.identifier.issn | 00223263 | |
| dc.identifier.uri | 10.1021/jo301694n | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/jo301694n | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/13366 | |
| dc.title | Vinyl azides derived from allenes: Thermolysis leading to multisubstituted 1,4-pyrazines and Mn(III)-catalyzed photochemical reaction leading to pyrroles | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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