Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na < inf > 26 < /inf > [Mo < inf > 142 < /inf > O < inf > 432 < /inf > (H < inf > 2 < /inf > O) < inf > 58 < /inf > H < inf > 14 < /inf > ] · ca. 300 H < inf > 2 < /inf > O
Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na < inf > 26 < /inf > [Mo < inf > 142 < /inf > O < inf > 432 < /inf > (H < inf > 2 < /inf > O) < inf > 58 < /inf > H < inf > 14 < /inf > ] · ca. 300 H < inf > 2 < /inf > O
| dc.contributor.author | Müller, Achim | |
| dc.contributor.author | Beugholt, Christian | |
| dc.contributor.author | Koop, Michael | |
| dc.contributor.author | Das, Samar K. | |
| dc.contributor.author | Schmidtmann, Marc | |
| dc.contributor.author | Bögge, Hartmut | |
| dc.date.accessioned | 2022-03-27T08:45:08Z | |
| dc.date.available | 2022-03-27T08:45:08Z | |
| dc.date.issued | 1999-01-01 | |
| dc.description.abstract | The syntheses and structures of the two mixed-valence crystalline molybdenum blue compounds Na26[Mo142O432(H2O) 58H14] · ca. 300 H2O (1) (containing the maximal number of well defined defects which influence the overall structure and the reactivity of the anionic cluster) and Na16[(MoO3)176(H2O) 63(CH3OH)17H16] · ca. 600 H2O · ca. 6 CH3OH (2) (obtained in an optimized high-yield synthesis) are reported with reference to the critical conditions required for the isolation of corresponding crystalline materials. | |
| dc.identifier.citation | Zeitschrift fur Anorganische und Allgemeine Chemie. v.625(12) | |
| dc.identifier.issn | 00442313 | |
| dc.identifier.uri | 10.1002/(sici)1521-3749(199912)625:12 < 1960::aid-zaac1960 > 3.0.co;2-a | |
| dc.identifier.uri | https://onlinelibrary.wiley.com/doi/10.1002/(SICI)1521-3749(199912)625:12 < 1960::AID-ZAAC1960 > 3.0.CO;2-A | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/11691 | |
| dc.subject | Cluster | |
| dc.subject | Defect structures | |
| dc.subject | Inorganic rings | |
| dc.subject | Mixed-valence compound | |
| dc.subject | Molybdenum blue | |
| dc.subject | Polyoxometallate | |
| dc.title | Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na < inf > 26 < /inf > [Mo < inf > 142 < /inf > O < inf > 432 < /inf > (H < inf > 2 < /inf > O) < inf > 58 < /inf > H < inf > 14 < /inf > ] · ca. 300 H < inf > 2 < /inf > O | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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