Mimicking dihydroxy acetone phosphate-utilizing aldolases through organocatalysis: A facile route to carbohydrates and aminosugars
Mimicking dihydroxy acetone phosphate-utilizing aldolases through organocatalysis: A facile route to carbohydrates and aminosugars
| dc.contributor.author | Suri, Jeff T. | |
| dc.contributor.author | Ramachary, Dhevalapally B. | |
| dc.contributor.author | Barbas, Carlos F. | |
| dc.date.accessioned | 2022-03-27T09:42:37Z | |
| dc.date.available | 2022-03-27T09:42:37Z | |
| dc.date.issued | 2005-03-31 | |
| dc.description.abstract | (Chemical Equation Presented) A practical and environmentally friendly organocatalytic strategy designed to mimic the DHAP aldolases has been developed and shown to be effective in the preparation of carbohydrates and aminosugars. (S)-Proline and (S)-2-pyrrolidine-tetrazole catalyzed the aldol reaction between dihydroxy acetone variants such as 1,3-dioxan-5-one and 2,2-dimethyl-1,3- dioxan-5-one with aldehydes to give the corresponding polyols in good yields with very high ees. © 2005 American Chemical Society. | |
| dc.identifier.citation | Organic Letters. v.7(7) | |
| dc.identifier.issn | 15237060 | |
| dc.identifier.uri | 10.1021/ol0502533 | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/ol0502533 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/13222 | |
| dc.title | Mimicking dihydroxy acetone phosphate-utilizing aldolases through organocatalysis: A facile route to carbohydrates and aminosugars | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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