Synthesis of cyclobutenediones and anhydrides from alkynes using the Fe(CO) < inf > 5 < /inf > /Me < inf > 3 < /inf > NO reagent system
Synthesis of cyclobutenediones and anhydrides from alkynes using the Fe(CO) < inf > 5 < /inf > /Me < inf > 3 < /inf > NO reagent system
| dc.contributor.author | Periasamy, Mariappan | |
| dc.contributor.author | Mukkanti, Amere | |
| dc.contributor.author | Shyam Raj, D. | |
| dc.date.accessioned | 2022-03-27T09:08:47Z | |
| dc.date.available | 2022-03-27T09:08:47Z | |
| dc.date.issued | 2004-12-20 | |
| dc.description.abstract | Coordinatively unsaturated "Fe(CO)4" species prepared using inexpensive Me3NO and Fe(CO)5 reacts with alkynes under ambient conditions to give cyclobutenediones in moderate to good yields (50-75%) after CuCl2·2H2O oxidation. The corresponding cyclic anhydrides are obtained in 60-80% yields when an excess of the amine oxide was used. | |
| dc.identifier.citation | Organometallics. v.23(26) | |
| dc.identifier.issn | 02767333 | |
| dc.identifier.uri | 10.1021/om049429f | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/om049429f | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12489 | |
| dc.title | Synthesis of cyclobutenediones and anhydrides from alkynes using the Fe(CO) < inf > 5 < /inf > /Me < inf > 3 < /inf > NO reagent system | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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