Michael-type addition to 2-nitrogalactal - A simple method to access 1,1-linked oligosaccharides

dc.contributor.author Balamurugan, Rengarajan
dc.contributor.author Pachamuthu, Kandasamy
dc.contributor.author Schmidt, Richard R.
dc.date.accessioned 2022-03-27T08:39:40Z
dc.date.available 2022-03-27T08:39:40Z
dc.date.issued 2005-01-05
dc.description.abstract Anomeric O-unprotected sugars add to 3,4,6-tri-O-benzyl-2-nitro-D-galactal to accomplish nitro group-containing 1,1-linked oligosaccharides in respectable yields with good selectivities. A 1:1 mixture of toluene and n-heptane has been found as the appropriate solvent system for these Michael-type additions. The nitro group-containing 1,1-linked oligosaccharides are easily convertible into interesting trehalosamine analogues.
dc.identifier.citation Synlett
dc.identifier.issn 09365214
dc.identifier.uri 10.1055/s-2004-836059
dc.identifier.uri http://www.thieme-connect.de/DOI/DOI?10.1055/s-2004-836059
dc.identifier.uri https://dspace.uohyd.ac.in/handle/1/11402
dc.subject 1,1-linked oligosaccharides
dc.subject 2-nitrogalactal
dc.subject Michael-type addition
dc.subject Nitro group
dc.subject O-unprotected sugars
dc.title Michael-type addition to 2-nitrogalactal - A simple method to access 1,1-linked oligosaccharides
dc.type Journal. Article
dspace.entity.type
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