Crystal and molecular structure of nitrato(6,6′-dimethyl-2,2′-bipyridine)silver(I). A dimer held by stacking and silver-silver interactions
Crystal and molecular structure of nitrato(6,6′-dimethyl-2,2′-bipyridine)silver(I). A dimer held by stacking and silver-silver interactions
| dc.contributor.author | Venkatalakshmi, Nandanavanam | |
| dc.contributor.author | Rajasekharan, Melath V. | |
| dc.contributor.author | Mathews, Irimpan I. | |
| dc.date.accessioned | 2022-03-27T09:17:42Z | |
| dc.date.available | 2022-03-27T09:17:42Z | |
| dc.date.issued | 1992-10-01 | |
| dc.description.abstract | The crystal and molecular structure of Ag(dmbp)NO3, where dmbp=6,6′-dimethyl-2,2′-bipyridine, has been determined. The crystal consists of dimers formed by two symmetry-related molecules. Each dimeric unit is held together by (weak) Ag-Ag and heteroaromatic ring stacking interactions. Stacking interactions lead to a slipped stack arrangement of the dimers. The coordination around silver is very nearly planar (tetrahedral distortion angle=15°), with the nitrate ion acting as an unsymmetrical chelating ligand. © 1992 Chapman & Hall. | |
| dc.identifier.citation | Transition Metal Chemistry. v.17(5) | |
| dc.identifier.issn | 03404285 | |
| dc.identifier.uri | 10.1007/BF02910731 | |
| dc.identifier.uri | http://link.springer.com/10.1007/BF02910731 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12712 | |
| dc.title | Crystal and molecular structure of nitrato(6,6′-dimethyl-2,2′-bipyridine)silver(I). A dimer held by stacking and silver-silver interactions | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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