Addition of titanium ester enolates to aldimines containing a chiral α-methylbenzylamine moiety: synthesis of chiral syn-β-amino esters
Addition of titanium ester enolates to aldimines containing a chiral α-methylbenzylamine moiety: synthesis of chiral syn-β-amino esters
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Date
2006-05-15
Authors
Periasamy, Mariappan
Suresh, Surisetti
Subramaniapillai, Selva Ganesan
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Abstract
Addition of titanium ester enolates to N-arylidene derivatives containing a (R)-α-methylbenzylamine moiety afforded (2S,3S,αR)-β-amino esters in 73-93% yields with 86:14 to 96:4 diastereomeric ratios. © 2006 Elsevier Ltd. All rights reserved.
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Tetrahedron Asymmetry. v.17(9)