Isolation of Blackberry-Shaped Nanoparticles of a Giant {Mo < inf > 72 < /inf > Fe < inf > 30 < /inf > } Cluster and Their Transformation to a Crystalline Nanoferric Molybdate
Isolation of Blackberry-Shaped Nanoparticles of a Giant {Mo < inf > 72 < /inf > Fe < inf > 30 < /inf > } Cluster and Their Transformation to a Crystalline Nanoferric Molybdate
| dc.contributor.author | Mekala, Raju | |
| dc.contributor.author | Supriya, Sabbani | |
| dc.contributor.author | Das, Samar K. | |
| dc.date.accessioned | 2022-03-27T08:42:02Z | |
| dc.date.available | 2022-03-27T08:42:02Z | |
| dc.date.issued | 2016-12-19 | |
| dc.description.abstract | When an aqueous solution of sodium molybdate is added to an aqueous solution of ferric chloride, acidified with acetic acid, a giant {Mo72Fe30} cluster is instantaneously formed as the amorphous substance Na2[Mo72Fe30O252(CH3COO)4(OH)16(H2O)108]·180 H2O (1). Compound 1 consists of aggregated nanovesicles of {Mo72Fe30} clusters, as confirmed by field-emission scanning electron microscopy and transmission electron microscopy images of 1. An aqueous suspension of 1 upon moderate heating results in the formation of crystalline nanoferric molybdate, which gives insight into understanding the formation of a yellow coating mineral, ferrimolybdite, frequently found on the ores of molybdenum. | |
| dc.identifier.citation | Inorganic Chemistry. v.55(24) | |
| dc.identifier.issn | 00201669 | |
| dc.identifier.uri | 10.1021/acs.inorgchem.6b02292 | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/acs.inorgchem.6b02292 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/11539 | |
| dc.title | Isolation of Blackberry-Shaped Nanoparticles of a Giant {Mo < inf > 72 < /inf > Fe < inf > 30 < /inf > } Cluster and Their Transformation to a Crystalline Nanoferric Molybdate | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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