Highly diastereoselective TiCl < inf > 4 < /inf > mediated addition of (E)-cinnamyl(tributyl)tin to α-keto esters
Highly diastereoselective TiCl < inf > 4 < /inf > mediated addition of (E)-cinnamyl(tributyl)tin to α-keto esters
| dc.contributor.author | Basavaiah, Deevi | |
| dc.contributor.author | Sreenivasulu, Bandaru | |
| dc.date.accessioned | 2022-03-27T09:02:55Z | |
| dc.date.available | 2022-03-27T09:02:55Z | |
| dc.date.issued | 2002-04-15 | |
| dc.description.abstract | Highly syn-(87-98%) diastereoselective addition of (E)-cinnamyl(tributyl)tin to α-keto esters under the influence of titanium tetrachloride, leading to the isolation of pure alkyl syn-2-aryl-2-hydroxy-3-phenylpent-4-enoates in 50-80% yields, is described. © 2002 Elsevier Science Ltd. All rights reserved. | |
| dc.identifier.citation | Tetrahedron Letters. v.43(16) | |
| dc.identifier.issn | 00404039 | |
| dc.identifier.uri | 10.1016/S0040-4039(02)00417-3 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S0040403902004173 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12328 | |
| dc.subject | α-keto esters | |
| dc.subject | Allylation | |
| dc.subject | Cinnamyl(tributyl)tin | |
| dc.subject | Diastereoselectivity | |
| dc.subject | Titanium tetrachloride | |
| dc.title | Highly diastereoselective TiCl < inf > 4 < /inf > mediated addition of (E)-cinnamyl(tributyl)tin to α-keto esters | |
| dc.type | Journal. Article | |
| dspace.entity.type |
Files
License bundle
1 - 1 of 1