Spontaneous resolution through helical association of a Cu-azamacrocyclic complex with Lindqvist-type isopolyanion

dc.contributor.author	Sarma, Monima
dc.contributor.author	Chatterjee, Tanmay
dc.contributor.author	Vindhya, Hanumanthugari
dc.contributor.author	Das, Samar K.
dc.date.accessioned	2022-03-27T08:42:55Z
dc.date.available	2022-03-27T08:42:55Z
dc.date.issued	2012-02-14
dc.description.abstract	Anionic metathesis reaction between the perchlorate salt of a copper-tetraazamacrocycle complex and the tetrabutylammonium salt of Lindqvist-type isopolyoxometalates in acetonitrile leads to the formation of two new inorganic-organic hybrid solids formulated as [Cu(L)(MeCN)][W 6O 19] (1) and [Cu(L)(MeCN)][Mo 6O 19] (2). Interestingly, both ion-pair complexes crystallize in a chiral space group P2 12 12 1. Crystallographic analysis of the obtained compounds reveals the occurrence of spontaneous resolution during crystallization. Both the enantiomorphs of compound 1 have been structurally characterized, whereas the resolution of compound 2 is rather poor. © 2012 The Royal Society of Chemistry.
dc.identifier.citation	Dalton Transactions. v.41(6)
dc.identifier.issn	14779226
dc.identifier.uri	10.1039/c1dt11987g
dc.identifier.uri	http://xlink.rsc.org/?DOI=C1DT11987G
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/11585
dc.title	Spontaneous resolution through helical association of a Cu-azamacrocyclic complex with Lindqvist-type isopolyanion
dc.type	Journal. Article
dspace.entity.type

Now showing 1 - 1 of 1