Synthesis and characterization of a tetrametallic coordination complex of tetrahydroxy-p-benzoquinone
Synthesis and characterization of a tetrametallic coordination complex of tetrahydroxy-p-benzoquinone
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Date
2014-03-15
Authors
Gupta, Deepak
Shankar, Bhaskaran
Elumalai, Palani
Shanmugam, Ramasamy
Mobin, Shaikh M.
Weisser, Fritz
Sarkar, Biprajit
Sathiyendiran, Malaichamy
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Abstract
A new tetrametallic coordination complex of tetrahydroxy-p-benzoquinone (THBQ = C6O2(OH)4) has been synthesized by a single step reaction of THBQ with Re2(CO)10 in the absence of an ancillary ligand. This is only the second report on the synthesis of a discrete, planar, tetrametallic coordination complex containing THBQ 4- anion and its crystal structure. © 2013 Elsevier Inc. All rights reserved.
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Keywords
Oxocarbon-tetraanion,
Rhenium,
Tetracarbonyl,
Tetrahydroxy-p-benzoquinone,
Tetranuclear complex
Citation
Journal of Organometallic Chemistry. v.754