The first use of tri(1-naphthyl)phosphine oxide as ligand for rhenium(I)- complexes from phosphine via a one-pot approach
The first use of tri(1-naphthyl)phosphine oxide as ligand for rhenium(I)- complexes from phosphine via a one-pot approach
| dc.contributor.author | Arumugam, Ramar | |
| dc.contributor.author | Shankar, Bhaskaran | |
| dc.contributor.author | Arumuganathan, T. | |
| dc.contributor.author | Sathiyendiran, Malaichamy | |
| dc.date.accessioned | 2022-03-27T08:35:35Z | |
| dc.date.available | 2022-03-27T08:35:35Z | |
| dc.date.issued | 2021-02-01 | |
| dc.description.abstract | Tri(1-naphthyl)phosphine oxide (Np3P=O) coordinated complexes fac-[{Re(CO)3(Np3P=O)}2L] (1-2) were prepared from tri(1-naphthyl)phosphine (Np3P), H2-L (2,5-dihydroxy-1,4-benzoquinone for 1/chloranilic acid for 2), and Re2(CO)10 in a multi-component one-pot approach. A hard Np3P=O was formed in situ from soft Np3P during the reaction process. The solid state structure of 2 reveals that chloranilato is sandwiched between two naphthyl units, controlled by both aromatic π⋅⋅⋅π⋅⋅⋅π- and Cl⋅⋅⋅π- contacts. This is the first report on metal-complexes of tri(1-naphthyl)phosphine oxide. | |
| dc.identifier.citation | Journal of Organometallic Chemistry. v.933 | |
| dc.identifier.issn | 0022328X | |
| dc.identifier.uri | 10.1016/j.jorganchem.2020.121657 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S0022328X2030560X | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/11087 | |
| dc.subject | 2,5-Dihydroxy-1,4-benzoquinone | |
| dc.subject | Chloranilic acid | |
| dc.subject | Rhenium | |
| dc.subject | Self-assembly | |
| dc.subject | Tri(1-naphthyl)phosphine | |
| dc.subject | Tri(1-naphthyl)phosphine oxide | |
| dc.title | The first use of tri(1-naphthyl)phosphine oxide as ligand for rhenium(I)- complexes from phosphine via a one-pot approach | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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