An unusual hydrogen addition of indolo-2,3-quinodimethanes to dimethylindoles in the presence of 1,3-azoles

dc.contributor.author	Perumal, P. T.
dc.contributor.author	Nagarajan, R.
dc.date.accessioned	2022-03-27T08:40:53Z
dc.date.available	2022-03-27T08:40:53Z
dc.date.issued	2006-03-01
dc.description.abstract	Indolo-2,3-quinodimethane generated in situ from bis-(bromomethyl)indole with NaI/DMF at 70°C was expected to undergo cycloaddition with 1,3-azoles to give carboline derivatives, which form the backbone of many indole alkaloids. However, the reaction did not give the anticipated product but proceeded via hydrogen addition to exocyclic methylene groups, furnishing dimethylindoles in good yields. © Indian Academy of Sciences.
dc.identifier.citation	Journal of Chemical Sciences. v.118(2)
dc.identifier.issn	02534134
dc.identifier.uri	10.1007/BF02708473
dc.identifier.uri	http://link.springer.com/10.1007/BF02708473
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/11476
dc.subject	1,3-azoles
dc.subject	Bis-(bromomethyl)indole
dc.subject	Dimethylindoles
dc.subject	Hydrogen addition
dc.subject	Indolo-2,3-quinodimethane
dc.title	An unusual hydrogen addition of indolo-2,3-quinodimethanes to dimethylindoles in the presence of 1,3-azoles
dc.type	Journal. Article
dspace.entity.type

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