Isomerization of 1-alkenes using the Na < inf > 2 < /inf > Fe(CO) < inf > 4 < /inf > /CuCl and Na < inf > 2 < /inf > Fe(CO) < inf > 4 < /inf > /BrCH < inf > 2 < /inf > CH < inf > 2 < /inf >  Br reagent systems

dc.contributor.author	Reddy, Malladi Rama
dc.contributor.author	Periasamy, Mariappan
dc.date.accessioned	2022-03-27T09:11:25Z
dc.date.available	2022-03-27T09:11:25Z
dc.date.issued	1995-04-05
dc.description.abstract	The reagent Na2Fe(CO)4 prepared in situ in THF by the reduction of Fe(CO)5 with sodium naphthalenide reacts with certain alkenes in the presence of CuCl to bring about isomerization of the alkenes. Thus the 1-alkenes (1-dodecene, 1-decene, safrole and allyl benzene) are isomerized to trans-2-alkenes, and β-pinene is isomerized to α-pinene. Reactions involving BrCH2CH2Br in place of CuCl give similar results. © 1995.
dc.identifier.citation	Journal of Organometallic Chemistry. v.491(1-2)
dc.identifier.issn	0022328X
dc.identifier.uri	10.1016/0022-328X(94)05243-5
dc.identifier.uri	https://www.sciencedirect.com/science/article/abs/pii/0022328X94052435
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/12558
dc.subject	Copper(I) chloride
dc.subject	Iron pentacarbonyl
dc.subject	Iron tetracarbonyl
dc.subject	Iron-copper bonds
dc.subject	Isomerization
dc.subject	Supernucleophile
dc.title	Isomerization of 1-alkenes using the Na < inf > 2 < /inf > Fe(CO) < inf > 4 < /inf > /CuCl and Na < inf > 2 < /inf > Fe(CO) < inf > 4 < /inf > /BrCH < inf > 2 < /inf > CH < inf > 2 < /inf > Br reagent systems
dc.type	Journal. Article
dspace.entity.type

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