A one-dimensional assembly of copper(II) polyhedra via dual use of hydrogen-bonding and π-π interaction
A one-dimensional assembly of copper(II) polyhedra via dual use of hydrogen-bonding and π-π interaction
| dc.contributor.author | Sangeetha, Nimma Rajaiah | |
| dc.contributor.author | Pal, Satyanarayan | |
| dc.contributor.author | Anson, Christopher E. | |
| dc.contributor.author | Powell, Annie K. | |
| dc.contributor.author | Pal, Samudranil | |
| dc.date.accessioned | 2022-03-27T08:47:51Z | |
| dc.date.available | 2022-03-27T08:47:51Z | |
| dc.date.issued | 2000-10-09 | |
| dc.description.abstract | A copper(II) complex [Cu(Hpadh)Cl2] with pyridine-N, imine-N and amide-O coordinating 2-pyridine-carboxaldehyde 4-dimethylaminobenzoylhydrazone (Hpadh) has been synthesized and structurally characterized. In the solid state, each square-pyramidal Cu(Hpadh)Cl2 unit is connected to one neighbour by a pair of hydrogen bonds between the amide-H and the apical chloride and to the other by a couple of π-π interactions between the aromatic rings of the coordinated ligands forming a novel chain-like arrangement of copper(II) centres with successive long and short Cu ··· Cu distances. Variable temperature (300-18 K) magnetic susceptibility measurements showed that the complex is essentially Curie paramagnetic. (C) 2000 Elsevier Science S.A. | |
| dc.identifier.citation | Inorganic Chemistry Communications. v.3(8) | |
| dc.identifier.issn | 13877003 | |
| dc.identifier.uri | 10.1016/S1387-7003(00)00103-9 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S1387700300001039 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/11809 | |
| dc.subject | π-π interaction | |
| dc.subject | Copper(II) complex | |
| dc.subject | Hydrogen bonding | |
| dc.subject | Self-assembly | |
| dc.title | A one-dimensional assembly of copper(II) polyhedra via dual use of hydrogen-bonding and π-π interaction | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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