A Channel-Forming Polyiodide Network in [Cu(dafone) < inf > 3 < /inf > ]I < inf > 12 < /inf > . A Tris Chelate of Dafone and a New Planar Structure for the I < inf > 12 < /inf > < sup > 2- < /sup > Ion (Dafone = 4,5-Diazafluoren-9-one)
A Channel-Forming Polyiodide Network in [Cu(dafone) < inf > 3 < /inf > ]I < inf > 12 < /inf > . A Tris Chelate of Dafone and a New Planar Structure for the I < inf > 12 < /inf > < sup > 2- < /sup > Ion (Dafone = 4,5-Diazafluoren-9-one)
| dc.contributor.author | Menon, Sindhu | |
| dc.contributor.author | Rajasekharan, M. V. | |
| dc.date.accessioned | 2022-03-27T09:17:04Z | |
| dc.date.available | 2022-03-27T09:17:04Z | |
| dc.date.issued | 1997-01-01 | |
| dc.description.abstract | Treatment of an aqueous solution of copper(II) acetate, dafone, and KI with I2 in CH2Cl2 leads to the formation of Cu(dafone)3I12 (1). 1 crystallizes in the orthorhombic system, space group Pbcn, with a = 22.902(4) Å, b = 11.104(2) Å, c = 18.992(7) Å, and Z = 4. Cu(dafone)32+ is the first tris chelate of dafone and is stabilized by a channel-forming network of planar I122- ions. Temperature dependence of the EPR spectrum indicates fluxionality of the cation. | |
| dc.identifier.citation | Inorganic Chemistry. v.36(22) | |
| dc.identifier.issn | 00201669 | |
| dc.identifier.uri | 10.1021/ic970087y | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/ic970087y | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12697 | |
| dc.title | A Channel-Forming Polyiodide Network in [Cu(dafone) < inf > 3 < /inf > ]I < inf > 12 < /inf > . A Tris Chelate of Dafone and a New Planar Structure for the I < inf > 12 < /inf > < sup > 2- < /sup > Ion (Dafone = 4,5-Diazafluoren-9-one) | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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