Gold-Catalyzed Regioselective Tetradehydro-Diels-Alder Reaction of Yne-Ynamides: Access to 2,3-Dihydrobenzo[f]indoles

dc.contributor.author	Prabagar, B.
dc.contributor.author	Dutta, Shubham
dc.contributor.author	Gandon, Vincent
dc.contributor.author	Sahoo, Akhila K.
dc.date.accessioned	2022-03-27T09:46:09Z
dc.date.available	2022-03-27T09:46:09Z
dc.date.issued	2019-07-01
dc.description.abstract	Presented herein is a gold(I) catalyzed intramolecular tetradehydro-Diels-Alder (TDDA) reaction of alkyne-tethered-ynamides for the construction of structurally complex 2,3-dihydrobenzo[f]indole derivatives. The mechanism of the regioselective benzannulation reaction was rationalized by means of density functional theory (DFT) calculations. Substrates having an aryl group at the ynamide terminus are exclusively participating in this TDDA reaction under gold catalysis.
dc.identifier.citation	Asian Journal of Organic Chemistry. v.8(7)
dc.identifier.issn	21935807
dc.identifier.uri	10.1002/ajoc.201900225
dc.identifier.uri	https://onlinelibrary.wiley.com/doi/10.1002/ajoc.201900225
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/13285
dc.subject	benzo[f]indoles
dc.subject	cycloaddition
dc.subject	dehydro-Diels-Alder reaction
dc.subject	gold
dc.subject	yne-ynamides
dc.title	Gold-Catalyzed Regioselective Tetradehydro-Diels-Alder Reaction of Yne-Ynamides: Access to 2,3-Dihydrobenzo[f]indoles
dc.type	Journal. Article
dspace.entity.type

Now showing 1 - 1 of 1