Synthesis and characterization of binuclear manganese carbonyl complex of 1,4-bis(2-(2′-hydroxyphenyl)benzimidazol-1-yl)benzene and dimethylaminopyridine

dc.contributor.author Mishra, Isha
dc.contributor.author Priyatharsini, Maruthupandiyan
dc.contributor.author Sathiyendiran, Malaichamy
dc.date.accessioned 2022-03-27T08:35:34Z
dc.date.available 2022-03-27T08:35:34Z
dc.date.issued 2021-09-15
dc.description.abstract A neutral heteroleptic binuclear complex fac-[{Mn(CO)3(Py′)}2(L)] with Mn⋅⋅⋅Mn separation of ~13.5 Å was synthesized using Mn2(CO)10, 1,4-bis(2-(2′-hydroxyphenyl)benzimidazol-1-yl)benzene (H2-L), 4-dimethylaminopyridine (Py′), and trimethylamine N-oxide (Me3NO) via one-pot approach. Complex 1 adopts a helical structure in the solid-state.
dc.identifier.citation Journal of Organometallic Chemistry. v.949
dc.identifier.issn 0022328X
dc.identifier.uri 10.1016/j.jorganchem.2021.121934
dc.identifier.uri https://www.sciencedirect.com/science/article/abs/pii/S0022328X21002552
dc.identifier.uri https://dspace.uohyd.ac.in/handle/1/11085
dc.subject Chelates
dc.subject Dimethylaminopyridine
dc.subject Helical structure
dc.subject Hydroxyphenyl- benzimidazole
dc.subject Manganese
dc.subject Organometallics
dc.title Synthesis and characterization of binuclear manganese carbonyl complex of 1,4-bis(2-(2′-hydroxyphenyl)benzimidazol-1-yl)benzene and dimethylaminopyridine
dc.type Journal. Article
dspace.entity.type
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