Stereoselective transformation of Baylis-Hillman adducts into (3E)-3- (alkoxymethyl)alk-3-en-2-ones
Stereoselective transformation of Baylis-Hillman adducts into (3E)-3- (alkoxymethyl)alk-3-en-2-ones
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Date
2000-01-01
Authors
Basavaiah, Deevi
Suguna Hyma, Rachakonda
Muthukumaran, Kannan
Kumaragurubaran, Nagaswamy
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Abstract
The pure (3E)-3-(methoxymethyl)alk-3-en-2-ones and (3E)-3- (ethoxymethyl)alk-3-en-2-ones are formed in the acid induced reaction of 4- hydroxy-3-methylenealkan-2-ones with methanol and ethanol, respectively.
Description
Keywords
(3E)-3-(alkoxymethyl)alk-3-en- 2-ones,
Alcoholysis,
Baylis-Hillman reaction,
Stereoselectivity,
Trisubstituted alkenes
Citation
Synthesis