Organoantimony(V) oxido cubane cluster [(p-X-C < inf > 6 < /inf > H < inf > 4 < /inf > Sb) < inf > 4 < /inf > (O) < inf > 4- < /inf > (Ph < inf > 2 < /inf > SiO < inf > 2 < /inf > )] (X = Cl, Br) stabilized by diphenyldisiloxides
Organoantimony(V) oxido cubane cluster [(p-X-C < inf > 6 < /inf > H < inf > 4 < /inf > Sb) < inf > 4 < /inf > (O) < inf > 4- < /inf > (Ph < inf > 2 < /inf > SiO < inf > 2 < /inf > )] (X = Cl, Br) stabilized by diphenyldisiloxides
| dc.contributor.author | Santhana Raj Prabhu, M. | |
| dc.contributor.author | Jami, Ananda Kumar | |
| dc.contributor.author | Baskar, Viswanathan | |
| dc.date.accessioned | 2022-03-27T09:00:00Z | |
| dc.date.available | 2022-03-27T09:00:00Z | |
| dc.date.issued | 2009-07-13 | |
| dc.description.abstract | Reaction of (p-halophenyl)stibonic acid with diphenylsilanediol (in ratio 1:1) in refluxing toluene for 6 h afforded colorless crystalline products in high yields. Singlecrystal X-ray structural elucidation reveals the formation of'theproducts [(P-Cl-C6H4Sb)4(O) 4(Ph2SiO2)4 ](1) and [(P-Br-C 6H4Sb)4(O)4(Ph2SiO 2)4] (2), respectively. The clusters 1 and 2 were isostructural; the core consists of a distorted Sb4O4 cubane framework with the siloxides acting as bridging ligands across the antimony atoms present at alternate corners of the cube. © 2009 American Chemical Society. | |
| dc.identifier.citation | Organometallics. v.28(13) | |
| dc.identifier.issn | 02767333 | |
| dc.identifier.uri | 10.1021/om900244t | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/om900244t | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12240 | |
| dc.title | Organoantimony(V) oxido cubane cluster [(p-X-C < inf > 6 < /inf > H < inf > 4 < /inf > Sb) < inf > 4 < /inf > (O) < inf > 4- < /inf > (Ph < inf > 2 < /inf > SiO < inf > 2 < /inf > )] (X = Cl, Br) stabilized by diphenyldisiloxides | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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