Structure of [2-(aminomethyl)pyridine]silver(I) nitrate and EPR studies of its oxidation product
Structure of [2-(aminomethyl)pyridine]silver(I) nitrate and EPR studies of its oxidation product
| dc.contributor.author | Swarnabala, G. | |
| dc.contributor.author | Rajasekharan, M. V. | |
| dc.date.accessioned | 2022-03-27T09:17:07Z | |
| dc.date.available | 2022-03-27T09:17:07Z | |
| dc.date.issued | 1996-12-17 | |
| dc.description.abstract | Reaction of AgNO3 with excess 2-(aminomethyl)pyridine (amp) in water led to the crystallization of Ag(amp)NO3 (1). Nearly linear coordination of silver(I) by pyridine-N and amino-N from two different amp molecules results in a polymeric chain structure of 1. The packing is stabilized by ring-ring stacking interactions between two inversion-related polymer chains. Oxidation of 1 with (NH4)2S2O8 resulted in an orange solution from which a magnetically dilute AgII complex was crystallized by the addition of NH4PF6. It gave a well-resolved EPR spectrum and is formulated as silver(II) picolinate co-crystallized with NH4PF6. Copyright © 1996 Elsevier Science Ltd. | |
| dc.identifier.citation | Polyhedron. v.16(6) | |
| dc.identifier.issn | 02775387 | |
| dc.identifier.uri | 10.1016/S0277-5387(96)00360-9 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S0277538796003609 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12698 | |
| dc.subject | EPR | |
| dc.subject | Polymeric coordination compound | |
| dc.subject | Silver(I) | |
| dc.subject | Silver(II) | |
| dc.title | Structure of [2-(aminomethyl)pyridine]silver(I) nitrate and EPR studies of its oxidation product | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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