Fate of a giant {Mo < inf > 72 < /inf > Fe < inf > 30 < /inf > }-type polyoxometalate cluster in an aqueous solution at higher temperature: Understanding related keplerate chemistry, from molecule to material
Fate of a giant {Mo < inf > 72 < /inf > Fe < inf > 30 < /inf > }-type polyoxometalate cluster in an aqueous solution at higher temperature: Understanding related keplerate chemistry, from molecule to material
| dc.contributor.author | Mekala, Raju | |
| dc.contributor.author | Supriya, Sabbani | |
| dc.contributor.author | Das, Samar K. | |
| dc.date.accessioned | 2022-03-27T08:42:29Z | |
| dc.date.available | 2022-03-27T08:42:29Z | |
| dc.date.issued | 2013-09-02 | |
| dc.description.abstract | When the giant icosahedral {Mo72Fe30} cluster containing compound [Mo72Fe30O252(CH 3COO)12{Mo2O7(H2O)} 2{H2Mo2O8(H2O)}(H 2O)91]·150H2O (1) is refluxed in water for 36 h, it results in the formation of nanoiron molybdate, Fe 2(MoO4)3, in the form of a yellow precipitate; this simple approach not only generates nanoferric molybdate at a moderate temperature but also helps to understand the stability of {Mo 72Fe30} in terms of the linker-pentagon complementary relationship. © 2013 American Chemical Society. | |
| dc.identifier.citation | Inorganic Chemistry. v.52(17) | |
| dc.identifier.issn | 00201669 | |
| dc.identifier.uri | 10.1021/ic401281x | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/ic401281x | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/11563 | |
| dc.title | Fate of a giant {Mo < inf > 72 < /inf > Fe < inf > 30 < /inf > }-type polyoxometalate cluster in an aqueous solution at higher temperature: Understanding related keplerate chemistry, from molecule to material | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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