The CoCl < inf > 2 < /inf > /Ph(Et) < inf > 2 < /inf > N:BH < inf > 3 < /inf > /CO system: Reactions of the borane and cobalt carbonyl species
The CoCl < inf > 2 < /inf > /Ph(Et) < inf > 2 < /inf > N:BH < inf > 3 < /inf > /CO system: Reactions of the borane and cobalt carbonyl species
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Date
1998-02-25
Authors
Rao, M. Lakshmi Narayana
Periasamy, Mariappan
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Abstract
The CoCl2/Ph(Et)2N:BH3/CO system is useful for the hydroboration and carbonylation of alkenes to obtain the corresponding dialkyl ketones. The cobalt carbonyl species formed in situ in this way is also useful for hydroacylation-cyclisation of norbornene and for the Pauson-Khand reaction.
Description
Keywords
Alkene,
Carbonylation,
Carbonylative cyclisations,
Cobalt carbonyl reagents,
Dialkylketone,
Hydroboration
Citation
Journal of Organometallic Chemistry. v.553(1-2)