Dinuclear triple helical Mn(III), Fe(III) and Co(III) complexes
Dinuclear triple helical Mn(III), Fe(III) and Co(III) complexes
| dc.contributor.author | Sreerama, Subramanya Gupta | |
| dc.contributor.author | Mukhopadhyay, Abhik | |
| dc.contributor.author | Pal, Samudranil | |
| dc.date.accessioned | 2022-03-27T08:46:50Z | |
| dc.date.available | 2022-03-27T08:46:50Z | |
| dc.date.issued | 2007-09-20 | |
| dc.description.abstract | Synthesis, characterization and physical properties of the dinuclear triple helical complexes [Mn2(μ-L)3] (1), [Fe2(μ-L)3] (2) and [Co2(μ-L)3] (3) with the tetradentate Schiff base (H2L) derived from 1 mol equiv. of hydrazine and 2 mole equiv. of 2-hydroxy-1-naphthaldehyde are described. Triple helical molecular structures of 2 and 3 have been confirmed by X-ray crystallography. Magnetic susceptibility measurements reveal complex 3 is diamagnetic while a weak antiferromagnetic interaction is operative between the metal centres in both 1 and 2. © 2007 Elsevier Ltd. All rights reserved. | |
| dc.identifier.citation | Polyhedron. v.26(15) | |
| dc.identifier.issn | 02775387 | |
| dc.identifier.uri | 10.1016/j.poly.2007.05.004 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S0277538707002902 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/11766 | |
| dc.subject | Crystal structures | |
| dc.subject | Diazine ligand | |
| dc.subject | Dinuclear complexes | |
| dc.subject | Magnetic properties | |
| dc.subject | Triple helicates | |
| dc.title | Dinuclear triple helical Mn(III), Fe(III) and Co(III) complexes | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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