Total synthesis of (±)-grimaldone, epigrimaldone and α-cuparenones
Total synthesis of (±)-grimaldone, epigrimaldone and α-cuparenones
| dc.contributor.author | Srikrishna, A. | |
| dc.contributor.author | Ramachary, D. B. | |
| dc.date.accessioned | 2022-03-27T09:42:17Z | |
| dc.date.available | 2022-03-27T09:42:17Z | |
| dc.date.issued | 2006-05-01 | |
| dc.description.abstract | Total synthesis of (±)-grimaldone, epigrimaldone and α-cuparenone has been described. A combination of orthoester Claisen rearrangement, an acid catalysed rearrangement of a diazoketone for the generation of bicyclo[4.2.1]nonanedione, a retro-Claisen condensation and an intramolecular diazoketone cyclopropanation reaction have been employed for the construction of three contiguous quaternary atoms present in grimaldone and epigrimaldones. | |
| dc.identifier.citation | Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry. v.45(5) | |
| dc.identifier.issn | 03764699 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/13216 | |
| dc.subject | α-cuparenone | |
| dc.subject | Claisen rearrangement | |
| dc.subject | Cyclopropanation reaction | |
| dc.subject | Diazoketone | |
| dc.subject | Epigrimaldone | |
| dc.subject | Grimaldone | |
| dc.subject | Retro-Claisen condensation | |
| dc.title | Total synthesis of (±)-grimaldone, epigrimaldone and α-cuparenones | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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