Oxidative addition reactions of cyclodiphosph(III)azanes

dc.contributor.author	Kumara Swamy, K. C.
dc.contributor.author	Kommana, Praveen
dc.contributor.author	Vijjulatha, M.
dc.contributor.author	Praveen Kumar, K.
dc.date.accessioned	2022-03-27T09:55:48Z
dc.date.available	2022-03-27T09:55:48Z
dc.date.issued	2001-12-01
dc.description.abstract	The ansa compound {[t-BuN)P]2[O-6-t-Bu-4-Me-C6H2]2CH2} (2) reacts with two mole equivalents of selenium to afford the bis(seleno) compound {[t-BuN)P(Se)]2[O-6-t-Bu-4-Me-C6,H2]2CH2} (3): under analogous conditions sulfur gives the P(III)-N-P(V) derivative {[(t-BuN)PN(t-Bu)P(S)][O-6-t-Bu-4-Me-C6H2]2CH2} (4). These reactions are compared with those using [(ArO)PN(t-Bu)]2 (5) and the macrocycle {[t-BuN-P]2(OCH2CMe2CH2O)}2(6).
dc.identifier.citation	Phosphorus, Sulfur and Silicon and Related Elements. v.168-169
dc.identifier.issn	10426507
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/13447
dc.subject	Cyclodiphosph(III)azanes
dc.subject	Oxidalive addition
dc.subject	X-ray structure
dc.title	Oxidative addition reactions of cyclodiphosph(III)azanes
dc.type	Journal. Article
dspace.entity.type

Now showing 1 - 1 of 1