Huge quantum symmetry effect in the O + O<inf>2</inf> exchange reaction

dc.contributor.author	Rao, Tammineni Rajagopala
dc.contributor.author	Guillon, Grégoire
dc.contributor.author	Mahapatra, Susanta
dc.contributor.author	Honvault, Pascal
dc.date.accessioned	2022-03-27T00:17:23Z
dc.date.available	2022-03-27T00:17:23Z
dc.date.issued	2015-02-19
dc.description.abstract	We report extensive, full quantum-mechanical calculations for the 16O + 16O16O → 16O16O + 16O collisions, for both inelastic and atom exchange processes, using a time-independent method based on hyperspherical coordinates. The rates obtained in the present study are much larger than the previously reported ones for this system. The discrepancy is attributed to a huge symmetry effect that was missing in the studies so far. This effect differs from the well-known isotope effect. Importance of this quantum effect is further confirmed by comparison with results for the 16O + 18O18O → 16O18O + 18O, exchange reaction.
dc.identifier.citation	Journal of Physical Chemistry Letters. v.6(4)
dc.identifier.uri	10.1021/jz5026257
dc.identifier.uri	https://pubs.acs.org/doi/10.1021/jz5026257
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/3275
dc.subject	exchange reactions
dc.subject	Ozone
dc.subject	permutation symmetry effect
dc.subject	quantum mechanical method
dc.subject	rate constant
dc.title	Huge quantum symmetry effect in the O + O<inf>2</inf> exchange reaction
dc.type	Journal. Article
dspace.entity.type

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