Linking icosahedral, strong molecular magnets {Mo < inf > 72 < /inf > /(VI)Fe < inf > 30 < /inf > /(III)} to layers - A solid-state reaction at room temperature

dc.contributor.author	Müller, Achim
dc.contributor.author	Krickemeyer, Erich
dc.contributor.author	Das, Samar K.
dc.contributor.author	Kögerler, Paul
dc.contributor.author	Sarkar, Sabyasachi
dc.contributor.author	Bögge, Hartmut
dc.contributor.author	Schmidtmann, Marc
dc.contributor.author	Sarkar, Shatarupa
dc.date.accessioned	2022-03-27T08:45:02Z
dc.date.available	2022-03-27T08:45:02Z
dc.date.issued	2000-05-02
dc.description.abstract	The by no means trivial, solid-state reaction for the condensation of {(Mo)Mo5}12Fe30 giant spheres commences through the water ligands and leads to oxo (or hydroxo) bridging. As the discrete icosahedral units approach each other, their oxygen atom bridges ultimately form covalent bonds (Fe-Fe 3.79 Å, see picture) to result in a symmetric layered structure.
dc.identifier.citation	Angewandte Chemie - International Edition. v.39(9)
dc.identifier.issn	14337851
dc.identifier.uri	10.1002/(SICI)1521-3773(20000502)39:9 < 1612::AID-ANIE1612 > 3.0.CO;2-L
dc.identifier.uri	https://onlinelibrary.wiley.com/doi/10.1002/(SICI)1521-3773(20000502)39:9 < 1612::AID-ANIE1612 > 3.0.CO;2-L
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/11686
dc.subject	Cluster compounds
dc.subject	Magnetic properties
dc.subject	Molybdenum
dc.subject	Polyoxometalates
dc.subject	Solid- state chemistry
dc.title	Linking icosahedral, strong molecular magnets {Mo < inf > 72 < /inf > /(VI)Fe < inf > 30 < /inf > /(III)} to layers - A solid-state reaction at room temperature
dc.type	Journal. Article
dspace.entity.type

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