New carbazole appended subporphyrin displaying intramolecular charge transfer and solid state fluorescence

dc.contributor.author Chandra, Brijesh
dc.contributor.author Mondal, Navendu
dc.contributor.author Sathish Kumar, B.
dc.contributor.author Panda, Pradeepta K.
dc.date.accessioned 2022-03-27T08:37:58Z
dc.date.available 2022-03-27T08:37:58Z
dc.date.issued 2016-04-01
dc.description.abstract A new subporphyrin namely, hydroxo-5,10,15-tri(N-propyl-3-carbazolyl)subporphyri natoboron(III) 6 has been synthesized via the reported litreture procedure by the condensation of pyridine-tri-N-pyrrolylborane with 9-propyl-9H-carbazole-3-carbaldehyde. Its porphyrin analog i.e. 5,10,15,20-tetra(N-propyl-3-carbazolyl)porphyrin has also been isolated from the reaction mixture, formed due to scrambling process and complexed with Zn(II). Photophysical properties of both subporphyrin and Zn(II)porphyrin have been studied in detail to confirm the intramolecular charge transfer process in subporphyrin analog. In addition, the ring contracted congener 6 also displays solid state fluorescence.
dc.identifier.citation Journal of Porphyrins and Phthalocyanines. v.20(1-4)
dc.identifier.issn 10884246
dc.identifier.uri 10.1142/S1088424616500255
dc.identifier.uri https://www.worldscientific.com/doi/abs/10.1142/S1088424616500255
dc.identifier.uri https://dspace.uohyd.ac.in/handle/1/11294
dc.subject carbazole
dc.subject contracted porphyrin
dc.subject intramolecular charge transfer
dc.subject solid state fluorescence
dc.subject subporphyrin
dc.title New carbazole appended subporphyrin displaying intramolecular charge transfer and solid state fluorescence
dc.type Journal. Article
dspace.entity.type
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