Silver hexafluoroantimonate-catalyzed direct α-alkylation of unactivated ketones

dc.contributor.author	Naveen, Naganaboina
dc.contributor.author	Koppolu, Srinivasa Rao
dc.contributor.author	Balamurugan, Rengarajan
dc.date.accessioned	2022-03-27T08:39:20Z
dc.date.available	2022-03-27T08:39:20Z
dc.date.issued	2015-05-04
dc.description.abstract	A practically simple and direct α-alkylation of unactivated ketones using benzylic alcohols has been achieved. The in situ formed acetals are the key for the success of the reaction. The catalyst, silver hexafluoroantimonate(V) (AgSbF6) provides double activation by converting the ketone into an enol ether via acetal and generation of carbocationic center at the benzylic position of the benzylic alcohol. The alcohols include benzylic propargyl alcohols, cinnamyl alcohols, and diarylmethanols.
dc.identifier.citation	Advanced Synthesis and Catalysis. v.357(7)
dc.identifier.issn	16154150
dc.identifier.uri	10.1002/adsc.201400870
dc.identifier.uri	https://onlinelibrary.wiley.com/doi/10.1002/adsc.201400870
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/11380
dc.subject	cinnamyl alcohols
dc.subject	diarylmethanols
dc.subject	ketones
dc.subject	propargylic alcohols
dc.subject	silver
dc.subject	α-alkylations
dc.title	Silver hexafluoroantimonate-catalyzed direct α-alkylation of unactivated ketones
dc.type	Journal. Article
dspace.entity.type

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