Chiral vicinal bis(amide) molecules: Polar/helical assemblies in crystals and second harmonic generation

dc.contributor.author Philip Anthony, S.
dc.contributor.author Basavaiah, K.
dc.contributor.author Radhakrishnan, T. P.
dc.date.accessioned 2022-03-27T08:52:46Z
dc.date.available 2022-03-27T08:52:46Z
dc.date.issued 2005-09-01
dc.description.abstract A family of organic and metal-organic materials based on chiral vicinal bis(amide) structures are developed. Subtle molecular structure variations give rise to polar and helical organizations in crystals of the two basic compounds N,N′-bis(benzoyl)-(1R,2R)-diaminocyclohexane and N,N′- bis(isonicotinoyl)-(1R,2R)-diaminocyclohexane; they exhibit the unusual syn and normal anti conformations of the bis(amide) group, respectively. The new materials exhibit appreciable thermal stability and optical transparency. Trends in their second harmonic generation capability are analyzed. © 2005 American Chemical Society.
dc.identifier.citation Crystal Growth and Design. v.5(5)
dc.identifier.issn 15287483
dc.identifier.uri 10.1021/cg0501231
dc.identifier.uri https://pubs.acs.org/doi/10.1021/cg0501231
dc.identifier.uri https://dspace.uohyd.ac.in/handle/1/11998
dc.title Chiral vicinal bis(amide) molecules: Polar/helical assemblies in crystals and second harmonic generation
dc.type Journal. Article
dspace.entity.type
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