Direct synthesis of α-substituted phosphonates
Direct synthesis of α-substituted phosphonates
| dc.contributor.author | Praveen Kumar, K. | |
| dc.contributor.author | Muthiah, C. | |
| dc.contributor.author | Kumaraswamy, Sudha | |
| dc.contributor.author | Kumara Swamy, K. C. | |
| dc.date.accessioned | 2022-03-27T09:56:00Z | |
| dc.date.available | 2022-03-27T09:56:00Z | |
| dc.date.issued | 2001-04-30 | |
| dc.description.abstract | The α-substituted phosphonates (OCH2CMe2CH2O)P(O)CH(X)(Ar) [X=Cl, OMe, NMe2 and OSiMe3], useful precursors for Horner-Wadsworth-Emmons reactions, are readily prepared by treating (OCH2CMe2CH2O)PX with an aromatic aldehyde. In the reaction of (OCH2CMe2CH2O)PCl with furfuraldehyde and cinnamaldehyde, the 5-chlorofurfurylphosphonate (OCH2CMe2CH2O)P(O)CH2 (5-Cl-C4H2O) and the γ-chlorophosphonate (OCH2CMe2CH2O)P(O)CH=CH-CH(Cl)Ph, respectively, are formed in good yields. © 2001 Elsevier Science Ltd. | |
| dc.identifier.citation | Tetrahedron Letters. v.42(18) | |
| dc.identifier.issn | 00404039 | |
| dc.identifier.uri | 10.1016/S0040-4039(01)00399-9 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S0040403901003999 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/13450 | |
| dc.subject | Abramov reaction | |
| dc.subject | Phosphonates | |
| dc.title | Direct synthesis of α-substituted phosphonates | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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