Chromatographically separable ruffled non-planar isomeric octaalkylporphycenes: Consequences of unsymmetrical substitution upon structure and photophysical properties

dc.contributor.author Pati, Narendra N.
dc.contributor.author Sahoo, Sameeta
dc.contributor.author Sahoo, Sipra S.
dc.contributor.author Banerjee, Dipanjan
dc.contributor.author Rao, S. Venugopal
dc.contributor.author Panda, Pradeepta K.
dc.date.accessioned 2022-03-27T08:37:45Z
dc.date.available 2022-03-27T08:37:45Z
dc.date.issued 2020-06-21
dc.description.abstract We herein report the first synthesis of two unsymmetrically substituted novel porphycenes, i.e. 2,7,12,13-tetraethyl-9,10,19,20-tetramethyl (OAPo-T) and 2,3,16,17-tetraethyl-9,10,19,20-tetramethyl (OAPo-C) porphycenes, via reductive McMurry coupling of unsymmetrically substituted diacylbipyrrole and isolated them by thin layer chromatography. They exhibit good solubility with a ruffled nonplanar structure and unique photophysical properties, including two photon absorbance.
dc.identifier.citation New Journal of Chemistry. v.44(23)
dc.identifier.issn 11440546
dc.identifier.uri 10.1039/d0nj01744b
dc.identifier.uri http://xlink.rsc.org/?DOI=D0NJ01744B
dc.identifier.uri https://dspace.uohyd.ac.in/handle/1/11277
dc.title Chromatographically separable ruffled non-planar isomeric octaalkylporphycenes: Consequences of unsymmetrical substitution upon structure and photophysical properties
dc.type Journal. Article
dspace.entity.type
Files
License bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
1.71 KB
Format:
Plain Text
Description: