AuCl < inf > 3 < /inf > /AgSbF < inf > 6 < /inf > -catalyzed rapid epoxide to carbonyl rearrangement
AuCl < inf > 3 < /inf > /AgSbF < inf > 6 < /inf > -catalyzed rapid epoxide to carbonyl rearrangement
| dc.contributor.author | Gudla, Vanajakshi | |
| dc.contributor.author | Balamurugan, Rengarajan | |
| dc.date.accessioned | 2022-03-27T08:39:27Z | |
| dc.date.available | 2022-03-27T08:39:27Z | |
| dc.date.issued | 2012-09-26 | |
| dc.description.abstract | An efficient epoxide to carbonyl rearrangement using catalytic AuCl 3/AgSbF 6 has been presented. The reactions are fast and high yielding. β-Hydrogen migration takes place exclusively when hydrogen and methyl or substituted methyl groups are present at β-carbon of epoxide. When phenyl/acetyl/benzoyl and hydrogen are available at same carbon atom, migration of the former is preferred over the latter. © 2012 Elsevier Ltd. All rights reserved. | |
| dc.identifier.citation | Tetrahedron Letters. v.53(39) | |
| dc.identifier.issn | 00404039 | |
| dc.identifier.uri | 10.1016/j.tetlet.2012.07.056 | |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S0040403912012312 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/11388 | |
| dc.subject | Epoxides | |
| dc.subject | Gold catalysis | |
| dc.subject | Meinwald rearrangement | |
| dc.subject | Rearrangement | |
| dc.title | AuCl < inf > 3 < /inf > /AgSbF < inf > 6 < /inf > -catalyzed rapid epoxide to carbonyl rearrangement | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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