Ladder and hexagonal hydrogen-bond networks from a self-complementary H-shaped tecton

dc.contributor.author Aitipamula, Srinivasulu
dc.contributor.author Nangia, Ashwini
dc.date.accessioned 2022-03-27T09:31:12Z
dc.date.available 2022-03-27T09:31:12Z
dc.date.issued 2005-01-01
dc.description.abstract Self-assembly of the H-shaped tecton 1,4-di[bis (4′-hydroxyphenyl) methyl]benzene 1 via O-H-⋯O hydrogen bonds leads to a ladder or hexagonal network depending on the included solvent molecule. MeOH and EtOH solvates of 1 have isostructural hexagonal networks whereas inclusion of MeCN or dioxane results in a ladder structure. The ladder rung distance is modularly expanded from 11 to 20 Å in the cocrystal of 1 with 4,4′-bipyridine. The novel H-tecton adds to the library of T- and Y-shaped and tetrahedral organic nodes for network construction.
dc.identifier.citation Supramolecular Chemistry. v.17(1-2)
dc.identifier.issn 10610278
dc.identifier.uri 10.1080/10610270412331328880
dc.identifier.uri https://www.tandfonline.com/doi/full/10.1080/10610270412331328880
dc.identifier.uri https://dspace.uohyd.ac.in/handle/1/13004
dc.subject Crystal engineering
dc.subject Crystal structure prediction
dc.subject Hexagonal
dc.subject Hydrogen bond
dc.subject Ladder
dc.subject Network
dc.title Ladder and hexagonal hydrogen-bond networks from a self-complementary H-shaped tecton
dc.type Journal. Conference Paper
dspace.entity.type
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