Hydrolysis of spirophosphoranes with a saturated 1,3,2-dioxaphosphorinane ring: X-ray Structure of the intermolecularly H-bonded phosphate ester (OCH < inf > 2 < /inf > CMe < inf > 2 < /inf > CH < inf > 2 < /inf > O) P(O) (2,2′-O-C < inf > 6 < /inf > H < inf > 4 < /inf > -C < inf > 6 < /inf > H < inf > 4 < /inf > OH)

dc.contributor.author	Swamy, K. C.Kumara
dc.contributor.author	Said, Musa A.
dc.contributor.author	Kumaraswamy, Sudha
dc.contributor.author	Herbst-Irmer, R.
dc.contributor.author	Pülm, Melanie
dc.date.accessioned	2022-03-27T09:57:16Z
dc.date.available	2022-03-27T09:57:16Z
dc.date.issued	1998-09-30
dc.description.abstract	Hydrolysis of (6,5), (6,7) and (6,8)-spirophosphoranes containing the six-membered ring P(OCH2CMe2CH2O) has been studied; in all the cases the six-membered phosphorinane ring is retained during the first stage of hydrolysis. The X-ray structure of one such product, (OCH2CMe2CH2O) P(O)(2,2′-O-C6H4-C6H4OH) which exhibits intermolecular H-bonding, has been determined.
dc.identifier.citation	Polyhedron. v.17(20)
dc.identifier.issn	02775387
dc.identifier.uri	10.1016/S0277-5387(98)00160-0
dc.identifier.uri	https://www.sciencedirect.com/science/article/abs/pii/S0277538798001600
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/13470
dc.subject	Hydrogen bonding
dc.subject	Hydrolysis
dc.subject	Phosphorinane
dc.subject	Spirophosphorane
dc.subject	X-ray structure
dc.title	Hydrolysis of spirophosphoranes with a saturated 1,3,2-dioxaphosphorinane ring: X-ray Structure of the intermolecularly H-bonded phosphate ester (OCH < inf > 2 < /inf > CMe < inf > 2 < /inf > CH < inf > 2 < /inf > O) P(O) (2,2′-O-C < inf > 6 < /inf > H < inf > 4 < /inf > -C < inf > 6 < /inf > H < inf > 4 < /inf > OH)
dc.type	Journal. Article
dspace.entity.type

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