Organic-free self-assembled copper sulfide microflowers

dc.contributor.author	Kumar, Baskaran Ganesh
dc.contributor.author	Muralidharan, Krishnamurthi
dc.date.accessioned	2022-03-27T08:33:43Z
dc.date.available	2022-03-27T08:33:43Z
dc.date.issued	2013-04-01
dc.description.abstract	The hexamethyldisilazane-assisted synthesis of organic-free copper sulfide microflowers is described herein. The synthetic method was developed in such a way as not to leave any trace of organic material in the copper sulfide nanoparticles after purification. The flowers were constructed by the self-assembly of nanoflakes. Copper sulfide was formed via an S-N polymeric intermediate, which drives the formation of copper sulfide by elmination of trimethylsilyl chloride as a key product. A reaction mechanism has been proposed based on the results of time-dependent NMR studies. The self-assembly and stability of the microflowers are explained on the basis of analytical data. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
dc.identifier.citation	European Journal of Inorganic Chemistry
dc.identifier.issn	14341948
dc.identifier.uri	10.1002/ejic.201201344
dc.identifier.uri	https://onlinelibrary.wiley.com/doi/10.1002/ejic.201201344
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/10767
dc.subject	Copper
dc.subject	Nanostructures
dc.subject	Reaction mechanisms
dc.subject	Self-assembly
dc.subject	Sulfur
dc.title	Organic-free self-assembled copper sulfide microflowers
dc.type	Journal. Article
dspace.entity.type

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